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KMID : 1059519860300050449
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Journal of the Korean Chemical Society
1986 Volume.30 No. 5 p.449 ~ p.455
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Studies on the Synthesis of Polymer Metal Complex and Its Application to Organic Reactions
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Whang Kyu-Ja
Kim Young-Ju
Lee Yong-Keun
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Abstract
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Various polymer metal complexes have been synthesized from anhydrous AlCl3, FeCl3, SbCl5, SnCl4 and ZnCl2 with cation exchange resin in carbon disulfide solvent. The forms of the surfaces and sectioned beads of these polymer metal complexes have been observed using scanning electron probe microanalyzer. To examine the catalytic activity of polymer metal complexes, the esterification of various dibasic acids with alcohols have been carried out. Polymer metal complexes were found to be the effective catalyst for esterification of dibasic carboxylic acids.
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